Work Group Prof. Dr. F. Temps

1991 - 1995

S. Dertinger, A. Geers, J. Kappert, F. Temps, J. W. Wiebrecht, "Rotation-Vibration State Resolved Unimolecular Dynamics of Highly Vibrationally Excited CH3O (X 2E): III. State Specific Dissociation Rates from Spectroscopic Line Profiles and Time Resolved Measurements", Faraday Discuss. Roy. Soc. 102, 31 - 52 (1995), invited paper.

F. Temps, "Intramolecular Dynamics and State Specific Unimolecular Dissociation of CH3O (X 2E)", in: Molecular Dynamics and Spectroscopy by Stimulated Emission Pumping, Eds. H. L. Dai und R. W. Field, World Scientific, Singapore, 1995, pp. 375, invited paper.

F. Temps, "Fortschritte der Reaktionskinetik", Nachrichten aus Chemie, Technik und Laboratorium, 195 - 197 (1995), invited paper.

T. J. Sears, F. Temps, H. Gg. Wagner, M. Wolf, "Far Infrared Laser Magnetic Resonance Spectroscopy of CH2Cl", J. Mol. Spectrosc. 168, 136 - 146 (1994).

T. Bérces. S. Dóbé, F. Temps, H. Gg. Wagner, H. Ziemer, "Formation of Methoxy and Hydroxymethyl Free Radicals in Selected Elementary Reactions", 25th Symposium (International) on Combustion, p. 775. The Combustion Institute, Pittsburgh, 1994.

S. Dóbé, F. Temps, H. Gg. Wagner, H. Ziemer, T. Bérces, "Kinetics of the Reaction Between Hydroxymethyl Radicals and Hydrogen Atoms", J. Phys. Chem. 98, 9792 - 9800 (1994).

A. Geers, J. Kappert, F. Temps, J. W. Wiebrecht, "Rotation-Vibration State Resolved Unimolecular Dynamics of Highly Vibrationally Excited CH3O (X 2E): II. Intramolecular Vibrational Dynamics of "C-O Stretch" States", J. Chem. Phys. 101, 3634 - 3648 (1994).

A. Geers, J. Kappert, F. Temps, J. W. Wiebrecht, "Rotation-Vibration State Resolved Unimolecular Dynamics of Highly Vibrationally Excited CH3O (X 2E): I. Stimulated Emission Pumping Spectra", J. Chem. Phys. 101, 3618 - 3633 (1994).

J. Nolte, F. Temps, H. Gg. Wagner, M. Wolf, and T. J. Sears, "Far Infrared Laser Magnetic Resonance Detection of CHD (X 3A")", J. Chem. Phys. 100, 8706 - 8712 (1994).

S. Dóbé, C. Oehlers, F. Temps, H. Gg. Wagner, H. Ziemer, "Observation of an H/D Isotope Exchange Channel in the Reaction D + H2CO", Ber. Bunsenges. Phys. Chem. 98, 754 - 757 (1994).

H. E. Radford, M. A. Moore, T. J. Sears, J. Grußdorf, J. Nolte, F. Temps, "Far Infrared Laser Magnetic Resonance of X 2A' trans-DOCO", J. Mol. Spectrosc. 165, 137 - 149 (1994).

J. Grußdorf, J. Nolte, F. Temps, H. Gg. Wagner, "Primary Products of the Elementary Reactions of CH2CO with F, Cl, and OH in the Gas Phase", Ber. Bunsenges. Phys. Chem. 98, 546 - 553 (1994).

J. Nolte, J. Grußdorf, F. Temps, H. Gg. Wagner, "Kinetics of the Reaction of HOCO with O2 in the Gas Phase", Z. Naturforsch. 48a, 1234 - 1238 (1993).

H. Kraus, C. Oehlers, F. Temps, H. Gg. Wagner, "Kinetics of the Reactions of CH2 (X 3B1) with Selected Polycyclic Aromatic Hydrocarbons at Temperatures between 296 K < T < 690 K", J. Phys. Chem. 97, 10989 - 10995 (1993).

A. Geers, J. Kappert, F. Temps, J. W. Wiebrecht, "Direct Measurements of State Specific Unimolecular Dissociation Rate Constants of Highly Excited Single Rotation Vibration Quantum States of CH3O (X 2E)", J. Chem. Phys. 99, 2271 - 2274 (1993).

A. Geers, J. Kappert, C. Stöck, F. Temps, J. W. Wiebrecht, "Quantenzustandsaufgelöste Untersuchungen der Schwingungsdynamik und unimolekularen Dissoziation hochangeregter Moleküle am Beispiel CH3O (X 2E) = H + H2CO: Neue Erkenntnisse über unimolekulare chemische Elementarreaktionen", Nachr. Akad. Wiss. Göttingen, Math.-Phys. Klasse, 13 - 30 (1993 [No. 2]), invited paper.

S. Dóbé, M. Otting, F. Temps, H. Gg. Wagner, H. Ziemer, "Fast Flow Studies of the Reaction CH2OH + HCI = CH3OH Cl. The Heat of Formation of Hydroxymethyl", Ber. Bunsenges. Phys. Chem. 97, 877 - 884 (1993).

H. Kraus, C. Oehlers, F. Temps, H. Gg. Wagner, M. Wolf, "Rate Constants for the Reaction of 3CH2 (X 3B1) with Selected Alkenes at Temperatures between 296 K < T < 728 K", Ber. Bunsenges. Phys. Chem. 97, 545 - 553 (1993).

A. Geers, J. Kappert, F. Temps, T. J. Sears, "Stimulated Emission Pumping Spectroscopy of CH3O (X 2E, v6): New Observations on the Jahn-Teller Effect", J. Chem. Phys. 98, 4297 - 4300 (1993).

U. Bley, F. Temps, "Collision-Induced Intersystem Crossing of CH2 from a 1A1 to X 3B1: A Case Study of the Mixed- State Model", J. Chem. Phys. 98, 1058 - 1072 (1993).

F. Temps, H. Gg. Wagner, M. Wolf: "Some Experiments concerning the Reactions of HCCO with C2H2, O2, NO, and NO2", Z. Phys. Chem. 176, 27 - 39 (1992).

U. Bley, M. Koch, F. Temps, H. Gg. Wagner, "Line-Broadening Measurements of CH2 (X 3B1) Rotational Transitions by Far Infrared Laser Magnetic Resonance", J. Mol. Spectrosc. 156, 154 - 163 (1992).

U. Bley, F. Temps, H. Gg. Wagner, M. Wolf, "Investigations of the Reaction between CH2 (X 3B1) and O2 in the Temperature Range 233 K < T < 433 K", Ber. Bunsenges. Phys. Chem. 96, 1043 - 1048 (1992).

F. Temps, H. Gg. Wagner, M. Wolf, "Far Infrared Laser Magnetic Resonance Detection of CH2Cl", Z. Naturforsch. 47a, 660 - 664 (1992).

C. Oehlers, F. Temps, H. Gg. Wagner, M. Wolf, "Kinetics of the Reaction of OH Radicals with CH2CO", Ber. Bunsenges. Phys. Chem. 96, 171 - 175 (1992).

F. Temps, H. Gg. Wagner, "Kinetics of Reactions of Prototypical Aromatic Hydrocarbons with O (3P) Atoms and CH2 (X 3B1) Radicals: A Comparative Study", ACS Symposium on Combustion Chemistry, National Meeting of the American Chemical Society, New York, 1991; Fuel Chemistry 36, 1469 - 1477 (1991).

A. Geers, J. Kappert, F. Temps, J. W. Wiebrecht, "Collisional Relaxation of CH3O (A 2A1, v= 1, K = 9, N = 9, J = 8.5) by He", Chem. Phys. Lett. 178, 317 - 324 (1991).

U. Bley, P. B. Davies, M. Grantz, T. J. Sears, F. Temps, "The FIR LMR Spectrum of FO2: Some Classic Examples of Anticrossing Resonances", Chem. Phys. 152, 281 - 292 (1991), invited paper.